Thermoplastic:
•Less rigid than thermosets, thermoplastics can soften upon heating and return to their original form.
•They are easily molded and extruded into films, fibers and packaging
•Thermoplastics have a linear or branched molecular structure which determines their strength and thermal behavior; they are flexible at ordinary temperatures.
•The service temperature range for thermoplastics is considerably lower than that for thermosets.
Thermoplastic: Molecular structure
Thermoplastic: General Characteristic and Applications
Polyethylene (PE):
•Range from low impact strength to nearly unbreakable.
•Good clarity to opaque (not clear)
•Service temperatures range from -40˚F to 200˚F.
•Near zero absorption
•Excellent chemical resistance and electrical properties
Low-density PE (LDPE):
•Good toughness with flexibility
•Low-temperature impact resistance
Uses:
•Blow molded containers, toys
•Hot melt adhesives
•Injection molded house wares
•Paperboard coating
•Wire insulation
Acrylic:
•Acrylic possess moderate strength, good optical properties, and water resistance.
•There are transparent but can made be solid and generally are resistant to chemicals and have good electrical resistance.
•Typical applications include lenses, lighted signs, displays, window glazing, automotive lenses, lighting fixtures and furniture.
Acrylonitrile-butadiene-styrene (ABS):
•ABS is dimensionally stable and rigid and has good resistance to impact, abrasion, chemicals and electricity, strength and toughness, and low temperature properties.
•Typical applications include pipes, fitting, chrome-plated plumbing supplies, helmets, tool handles, telephone, housing appliances and decorative panels.
Cellulosics:
•Cellulosics have a wide range of mechanical properties, depending on their composition.
•They can be made rigid, strong, and tough.
•Typical applications include tool handles, pens, knobs, frames for eyeglasses, safety goggles, helmets, tubing and pipes, lighting fixtures, toy and decorative part.
Fluorocarbons: (common trade name: teflon)
•Fluorocarbons possess good resistance to temperature, chemicals, weather and electricity, they also have unique nonadhesive properties and low friction.
•Typical applications include linings for chemical- processing equipment, nonstick coating for cookware, electrical insulation for high-temperature wire and cable and bearing.
Nylons
•Nylons have good mechanical properties and abrasion resistance.
•All nylons are hygroscopic (they absorb water).
•Moisture absorption reduces mechanical properties and increases part dimensions.
•Typical applications include gears, bearing, electrical part and wear resistant surfaces.
Polycarbonates
•Polycarbonates are versatile and have good mechanical and electrical properties; they also have high impact resistance and can be made resistant to chemical.
•Typical applications include safety helmets, optical lenses, bottles, food processing equipment, medical instruments.
Polyesters
•Polyesters have good mechanical, electrical, chemical properties, good abrasion resistance, and low friction.
•Typical applications include gears, pump and electromechanical components.
Polyethylene.
•Polyethelenes posses good electrical and chemical properties.
•Their mechanical properties depend on their composition and structure.
•There are three major classes of polyethylene:
-Low Density Polyethylene (LDPE)
-High Density Polyethylene (HDPE)
-Ultrahigh Molecular Weight Polyethylene (UHMWPE)
Polyethylene.
•Typical application for LDPE & HDPE include housewares, bottles, garbage cans, ducts, luggage, toys, tubing, bottle and packaging material.
•UHMWPE is used in parts requiring high impact toughness and abrasive wear resistance, example include artificial knee and hip joints.
Polypropylenes (PP)
•Polypropylenes have good mechanical, electrical and chemical properties and good resistance to tearing.
•The various forms of polypropylene have different melting points and hardnesses.
•Typical applications include automotive trim and components, medical devices, wire insulation, TV cabinets, pipes, fittings, drinking cups, dairy-product and juice containers and luggage.
Polystyrenes
•Polystyrenes are inexpensive, have generally average properties and are breakable
•Typical applications include disposable containers, packaging, foam insulation, radio, and TV components, housewares and toys.
Polysulfones
•Polysulfones have excellent resistance to heat, water and steam and are highly resistant to some chemicals, but are attacked by organic solvents.
•Typical applications include steam irons, coffeemakers, hot-water containers, medical equipment that requires sterilization, power-tool and electrical insulators.
Polyvinyl Chloride (PVC)
•PVC has wide range of properties, is inexpensive and water resistant, and can be made rigid or flexible.
•It is not suitable application that require strength and heat resistance.
•Rigid PVC is tough and hard and is used for signs and in the construction industry such as for pipes.
•Flexible PVC is used in wire and cable coatings, low-pressure flexible tubing and hose, footwear, upholstery, records, film sheet and coating.